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Organic chemistry

Organic chemistry

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Question 31

This question is about polymers.

a.

Many biological substances are polymers. Complete the details to state the type of monomer which forms each of the biological polymers:

  • Starch: ………………………………………\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots………………………………………
  • Enzyme: ………………………………………\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots………………………………………
  • RNA: ………………………………………\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots\ldots………………………………………
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b.

Look at the structure of the polymer called poly(propene):

[HH∣∣−C−C−∣∣HCH3]n \left[ \begin{array}{ccc} \text{H} & & \text{H} \\ | & & | \\ \kern-0.5em-\kern-0.5em\text{C} & \kern-0.5em-\kern-0.5em & \text{C}\kern-0.5em-\kern-0.5em \\ | & & | \\ \text{H} & & \text{CH}_3 \end{array} \right]_n ​H∣−C∣H​−​H∣C−∣CH3​​​n​

This polymer is made from a monomer. Draw or represent the structure of this monomer.

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c.

Polyesters are also polymers.

Look at the structure of a polyester:

[−C(=O)−□−C(=O)−O−◯−O−]n \left[ -\text{C}(=\text{O}) - \square - \text{C}(=\text{O}) - \text{O} - \bigcirc - \text{O}- \right]_n [−C(=O)−□−C(=O)−O−◯−O−]n​

This polymer is made from two different monomers.

Draw or write the chemical formulas of each different monomer (use □\square□ and ◯\bigcirc◯ to represent the central carbon chains).

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d.

Kevlar is a high-strength polyamide. It can be prepared in a laboratory by reacting terephthaloyl chloride with 1,4-phenylenediamine.

  • Terephthaloyl chloride is corrosive and reacts with moisture in the air to release toxic acidic fumes (HCl\text{HCl}HCl gas).
  • The solvent used (dichloromethane) is highly volatile and is a toxic inhalation hazard.

Describe and explain two precautions a chemist should take to carry out this experiment safely.

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Markscheme

Organic chemistry Questions

  1. GCSE
  2. /Chemistry
  3. /Organic chemistry

83 exam-style questions on OCR GCSE Chemistry Organic chemistry. Each one has a worked solution and a mark scheme showing where the marks go.

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