An analytical chemist investigates an unknown crystalline solid, compound XXX.
Which of the following correctly identifies the chemical formula of compound X X\,X and the simplified ionic equation for the reaction producing the precipitate in Test 1?
Formula: (NH4)2SO4(\text{NH}_4)_2\text{SO}_4(NH4)2SO4 ; Ionic equation: Ba2+(aq)+SO42−(aq)→BaSO4(s)\text{Ba}^{2+}(\text{aq}) + \text{SO}_4^{2-}(\text{aq}) \rightarrow \text{BaSO}_4(\text{s})Ba2+(aq)+SO42−(aq)→BaSO4(s)
Formula: NH4SO4\text{NH}_4\text{SO}_4NH4SO4 ; Ionic equation: Ba2+(aq)+SO42−(aq)→BaSO4(s)\text{Ba}^{2+}(\text{aq}) + \text{SO}_4^{2-}(\text{aq}) \rightarrow \text{BaSO}_4(\text{s})Ba2+(aq)+SO42−(aq)→BaSO4(s)
Formula: (NH4)2SO4(\text{NH}_4)_2\text{SO}_4(NH4)2SO4 ; Ionic equation: BaCl2(aq)+SO42−(aq)→BaSO4(s)+2Cl−(aq)\text{BaCl}_2(\text{aq}) + \text{SO}_4^{2-}(\text{aq}) \rightarrow \text{BaSO}_4(\text{s}) + 2\text{Cl}^-(\text{aq})BaCl2(aq)+SO42−(aq)→BaSO4(s)+2Cl−(aq)
Formula: (NH4)2SO3(\text{NH}_4)_2\text{SO}_3(NH4)2SO3 ; Ionic equation: Ba2+(aq)+SO32−(aq)→BaSO3(s)\text{Ba}^{2+}(\text{aq}) + \text{SO}_3^{2-}(\text{aq}) \rightarrow \text{BaSO}_3(\text{s})Ba2+(aq)+SO32−(aq)→BaSO3(s)