Hydrogen ion concentration decides the pH
pH
A number, usually from 0 to 14, that shows how acidic or alkaline a solution is.
Hydrogen ion concentration
The amount of hydrogen ions dissolved in each cubic decimetre of solution, written as [H+] and measured in mol/dm³.
- The square brackets in [H+][\text{H}^+][H+] stand for the concentration of hydrogen ions, measured in mol/dm3\text{mol/dm}^3mol/dm3.
- The higher the [H+][\text{H}^+][H+], the lower the pH and the more acidic the solution.
- The lower the [H+][\text{H}^+][H+], the higher the pH.
- Pure water contains a tiny concentration of hydrogen ions, 1×10−7 mol/dm31 \times 10^{-7}\,\text{mol/dm}^31×10−7mol/dm3, which gives it pH 7.
- For whole-number values the pH matches the power of ten, so [H+]=1×10−3 mol/dm3[\text{H}^+] = 1 \times 10^{-3}\,\text{mol/dm}^3[H+]=1×10−3mol/dm3 gives pH 3.
A pH value is a compact way of writing a hydrogen ion concentration, with a smaller pH number meaning more hydrogen ions.
Hydrogen ions in neutral, acidic and alkaline solutions
Neutral solution
A solution that is neither acidic nor alkaline, with a pH of 7.
- In a neutral solution at pH 7, the concentrations of hydrogen ions and hydroxide ions are equal.
- An acidic solution has more hydrogen ions than hydroxide ions, so its pH is below 7.
- An alkaline solution has fewer hydrogen ions than hydroxide ions, so its pH is above 7.
- Even at pH 12 some hydrogen ions are present, at 1×10−12 mol/dm31 \times 10^{-12}\,\text{mol/dm}^31×10−12mol/dm3.
- Adding acid raises the [H+][\text{H}^+][H+] and lowers the pH, while adding alkali removes hydrogen ions and raises the pH.
![The pH scale from 0 to 14 with corresponding indicator colours, showing hydrogen ion concentrations [H+] and hydroxide ion concentrations [OH-] in mol dm⁻³ from 10⁰ to 10⁻¹⁴.](/_next/image?url=https%3A%2F%2Fassets.mathsgenie.co.uk%2Fcontent-studio%2Fnotion-illustrations%2F3a9142830a338130a1efd2371fd738b3%2F1-8ecdc823d42cdf00-ph-scale-and-ion-concentrations-3a914283-genie.png&w=3840&q=75)
Do not say that an alkaline solution contains no hydrogen ions, because every aqueous solution contains some.
Each tenfold concentration increase lowers pH by one
- Multiplying [H+][\text{H}^+][H+] by ten lowers the pH by one.
- Going from 1×10−41 \times 10^{-4}1×10−4 to 1×10−3 mol/dm31 \times 10^{-3}\,\text{mol/dm}^31×10−3mol/dm3 gives ten times more hydrogen ions, and the pH falls from 4 to 3.
- Dividing [H+][\text{H}^+][H+] by ten raises the pH by one.
- Diluting a strong acid tenfold with water divides its [H+][\text{H}^+][H+] by ten, so pH 1 becomes pH 2.
- A change of two pH units means a factor of 10×10=10010 \times 10 = 10010×10=100 in [H+][\text{H}^+][H+], and three units means a factor of 100010001000.
Do not treat pH 2 as twice as acidic as pH 4, because pH 2 has 100100100 times the hydrogen ion concentration.
pH differences give the hydrogen ion concentration factor
- Subtract the smaller pH from the larger one to find the number of steps.
- Raise ten to that power to find the factor, so a difference of three gives 103=100010^3 = 1000103=1000.
- The solution with the lower pH has the higher hydrogen ion concentration.
- The same method works in reverse, so a solution with 100010001000 times fewer hydrogen ions has a pH three units higher.
- Lemon juice has a pH of about 2 and tomato juice a pH of about 4; compare their hydrogen ion concentrations.
- Find the difference in pH: 4−2=24 - 2 = 24−2=2.
- Convert the difference to a factor: 102=10010^2 = 100102=100.
- Lemon juice has the lower pH, so its hydrogen ion concentration is about 100100100 times greater than that of tomato juice.
- What is the pH of a solution with [H+]=1×10−5 mol/dm3[\text{H}^+] = 1 \times 10^{-5}\,\text{mol/dm}^3[H+]=1×10−5mol/dm3?
- How do the hydrogen ion and hydroxide ion concentrations compare in a neutral solution?
- What happens to the pH when [H+][\text{H}^+][H+] increases by a factor of ten?
- How many times greater is [H+][\text{H}^+][H+] at pH 3 than at pH 6?
- A strong acid of pH 1 is diluted tenfold with water; what is its new pH?