Energetics

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Question 13
Medium

One chemical reaction used to propel spacecraft is the combustion of hydrazine. The balanced symbol equation for this reaction is:

N2H4+O2→N2+2H2O\text{N}_2\text{H}_4 + \text{O}_2 \rightarrow \text{N}_2 + 2\text{H}_2\text{O}N2​H4​+O2​→N2​+2H2​O

A molecule of hydrazine (N2H4\text{N}_2\text{H}_4N2​H4​) contains four N−H\text{N}-\text{H}N−H bonds and one N−N\text{N}-\text{N}N−N bond. A molecule of oxygen (O2\text{O}_2O2​) contains one O=O\text{O}=\text{O}O=O bond. A molecule of nitrogen (N2\text{N}_2N2​) contains one N≡N\text{N}\equiv\text{N}N≡N bond. A molecule of water (H2O\text{H}_2\text{O}H2​O) contains two O−H\text{O}-\text{H}O−H bonds.

The table below shows the average bond energies:

BondBond energy (kJ/mol)
N−H\text{N}-\text{H}N−H391
N−N\text{N}-\text{N}N−N158
O=O\text{O}=\text{O}O=O498
N≡N\text{N}\equiv\text{N}N≡N945
O−H\text{O}-\text{H}O−H464
a.

Calculate the energy transferred when all the bonds form in the products.

[4]
b.

The energy transferred when all the bonds break in the reactants is 2220 kJ/mol2220\text{ kJ/mol}2220 kJ/mol. Use your answer to part (a) to calculate the overall energy change for this reaction.

[3]

Energetics Questions

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