Energetics

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Question 9
Medium

A student investigates the reaction of different metals with dilute nitric acid using a calorimeter setup:

Experimental Setup

a.

The student notices that the temperature rises when a metal is added to the acid. What name is given to this type of reaction?

[1]
b.

The metal potassium reacts with nitric acid, HNO3\text{HNO}_3HNO3​, to form potassium nitrate, KNO3\text{KNO}_3KNO3​, and hydrogen, H2\text{H}_2H2​. Write a balanced symbol equation for this reaction.

[2]
c.

The experiment is repeated with calcium and hydrochloric acid. Write down the name of the salt produced in this reaction.

[1]
d.

The student repeats the experiment with different metals. She repeats the experiment three times for each metal, measuring the temperature change in each experiment.

MetalTemperature change (∘C^{\circ}\text{C}∘C)
Trial 1Trial 2Trial 3
Calcium18.418.218.6
Iron5.19.85.3
Tin1.41.61.5

One of the student's results is anomalous. State the metal and the trial number for this anomalous result.

[1]
e.

Suggest a reason why this result could be anomalous.

[1]
f.

Calculate the mean temperature change for calcium. Give your answer to 1 decimal place.

[1]
g.

The student wants to improve her experiment to get more accurate results. Suggest an improvement to her experiment and give a reason for this improvement.

[2]
h.

The student concludes that the more reactive the metal is, the higher the temperature rise. Describe further tests the student can do to confirm her conclusion.

[1]
i.

Diagrammatically sketch or describe the reaction profile for the reaction between calcium and nitric acid.

Label on your description or drawing the:

  • reactants and products
  • overall energy change
  • activation energy.
[4]

Energetics Questions

  1. GCSE
  2. /Chemistry
  3. /Energetics