Concentration measures solute per volume of solution
Concentration
The amount of solute dissolved in a stated volume of solution, measured in g/dm³ or mol/dm³.
Solute
The substance that dissolves in a solvent to make a solution.
- A solution forms when a solute dissolves in a solvent, such as salt dissolving in water.
- A concentrated solution has a lot of solute in a given volume, while a dilute solution has only a little.
- Concentration can be measured in grams per cubic decimetre, written g/dm3\text{g/dm}^3g/dm3.
- One cubic decimetre is 1000 cm31000\,\text{cm}^31000cm3, which is the same as one litre.
- The volume used is the volume of the whole solution, not the volume of water that was added.
- Concentration can also be given in mol/dm3\text{mol/dm}^3mol/dm3, which uses the amount in moles of solute instead of its mass.
Concentration depends on two things only: how much solute there is and how much solution it is spread through.
Concentration equals mass of solute over volume
- The relationship is: concentration (g/dm3)=mass of solute (g)volume of solution (dm3)\text{concentration (g/dm}^3\text{)} = \frac{\text{mass of solute (g)}}{\text{volume of solution (dm}^3\text{)}}concentration (g/dm3)=volume of solution (dm3)mass of solute (g)
- Convert a volume in cm3\text{cm}^3cm3 into dm3\text{dm}^3dm3 by dividing by 1000 before using the equation.
- So 250 cm3250\,\text{cm}^3250cm3 is 0.250 dm30.250\,\text{dm}^30.250dm3.
- Rearranging gives mass of solute === concentration ×\times× volume, which tells you how much solid to weigh out.
- Making 2.00 dm32.00\,\text{dm}^32.00dm3 of a 15.0 g/dm315.0\,\text{g/dm}^315.0g/dm3 solution needs 15.0×2.00=30.0 g15.0 \times 2.00 = 30.0\,\text{g}15.0×2.00=30.0g of solute.
- Give every answer with its unit, because a number alone does not say whether it is a mass, a volume or a concentration.
- Calculate the concentration of a solution made by dissolving 5.00 g5.00\,\text{g}5.00g of sodium chloride in water to make 250 cm3250\,\text{cm}^3250cm3 of solution.
- Convert the volume: 250 cm3÷1000=0.250 dm3250\,\text{cm}^3 \div 1000 = 0.250\,\text{dm}^3250cm3÷1000=0.250dm3.
- Divide mass by volume: 5.00 g0.250 dm3=20.0 g/dm3\dfrac{5.00\,\text{g}}{0.250\,\text{dm}^3} = 20.0\,\text{g/dm}^30.250dm35.00g=20.0g/dm3.
How solute mass and volume affect concentration
- At a fixed volume, concentration is directly proportional to the mass of solute.
- Dissolving twice the mass of solute in the same volume doubles the concentration.
- For a fixed mass of solute, a larger volume of solution gives a lower concentration.
- Spreading the same mass through twice the volume halves the concentration.
- Doubling both the mass and the volume leaves the concentration unchanged.
- A sample of any size taken from a well-mixed solution has the same concentration as the rest of it.
Adding more squash to the same glass of water makes a stronger drink, while topping the glass up with water makes it weaker, although the amount of squash in the glass has not changed.
Diluting a solution lowers its concentration
- When water is added, the mass of solute stays the same.
- The volume of solution increases, so the concentration falls.
- Evaporating some of the water has the opposite effect, raising the concentration because the volume decreases while the solute stays.
- To find a new concentration, first work out the mass of solute present, then divide it by the new volume.
- Water is added to 50.0 cm350.0\,\text{cm}^350.0cm3 of a 40.0 g/dm340.0\,\text{g/dm}^340.0g/dm3 solution until its volume is 200 cm3200\,\text{cm}^3200cm3; find the new concentration.
- Mass of solute =40.0 g/dm3×0.0500 dm3=2.00 g= 40.0\,\text{g/dm}^3 \times 0.0500\,\text{dm}^3 = 2.00\,\text{g}=40.0g/dm3×0.0500dm3=2.00g.
- New concentration =2.00 g0.200 dm3=10.0 g/dm3= \dfrac{2.00\,\text{g}}{0.200\,\text{dm}^3} = 10.0\,\text{g/dm}^3=0.200dm32.00g=10.0g/dm3.
Making a solution of known concentration
- Weigh the solid accurately on a balance in a weighing boat or small beaker.
- Dissolve it in a small volume of distilled water in a beaker, stirring until no solid remains.
- Pour the solution into a volumetric flask and rinse the beaker and stirring rod into the flask, so no solute is left behind.
- Add distilled water until the bottom of the meniscus sits on the line, then stopper and invert the flask to mix.
- Divide the mass weighed by the volume of the flask in dm3\text{dm}^3dm3 to find the concentration.
When a question asks how a change affects concentration, say what happens to the mass of solute and what happens to the volume of solution, then state the effect.
- What does a concentration of 20.0 g/dm320.0\,\text{g/dm}^320.0g/dm3 mean?
- What is the concentration of 3.00 g3.00\,\text{g}3.00g of solute in 150 cm3150\,\text{cm}^3150cm3 of solution?
- What happens to the concentration if the same mass of solute is dissolved in twice the volume?
- Why does adding water lower the concentration of a solution?
- What mass of solute is needed to make 500 cm3500\,\text{cm}^3500cm3 of a 12.0 g/dm312.0\,\text{g/dm}^312.0g/dm3 solution?