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6.1.7 Comparing and selecting materials

Ceramics, polymers, composites and metals have typical properties

Definition

Ceramic

A hard, brittle, non-metallic material made by heating substances such as clay or sand to a high temperature, including pottery, bricks and glass.

Definition

Composite material

A material made by combining two or more different materials, usually fibres or particles held in a matrix, with properties different from those of each material alone.

  1. Glass is a ceramic made by melting sand with other substances, and it is hard, transparent and brittle.
  2. Clay ceramics, such as bricks, tiles and china, are made by shaping wet clay and heating it in a kiln, and they are hard, brittle and strong when squashed.
  3. Polymers, such as poly(ethene), have low densities, are often flexible and are good electrical and thermal insulators.
  4. Composites combine two materials, with fibres or particles of one set in a matrix of the other, to get properties that neither has alone.
  5. Metals are strong, dense, malleable and good conductors of heat and electricity, but many corrode.
Key Idea

Each class of material has typical properties, but the values for particular materials within a class can differ widely.

Quantitative data show how much materials differ

Definition

Density

The mass of a material per unit volume, usually measured in kg/m³ or g/cm³.

Definition

Tensile strength

The largest pulling force per unit area that a material can withstand before it breaks.

  1. Density data show that steel, at about 7800 kg/m37800\,\text{kg/m}^37800kg/m3, is roughly eight times as dense as poly(ethene), at about 950 kg/m3950\,\text{kg/m}^3950kg/m3.
  2. A carbon-fibre composite can have a tensile strength of about 600 MPa600\,\text{MPa}600MPa, compared with about 400 MPa400\,\text{MPa}400MPa for steel and about 30 MPa30\,\text{MPa}30MPa for poly(ethene).
  3. Clay ceramics are strong when compressed but weak when stretched, with a tensile strength often below 10 MPa10\,\text{MPa}10MPa.
  4. Melting points range from about 110 ∘C110\ ^{\circ}\text{C}110 ∘C for poly(ethene) to about 1500 ∘C1500\ ^{\circ}\text{C}1500 ∘C for steel.
  5. Aluminium conducts heat about 200 times better than glass, which is why saucepans are made of metal but have polymer handles.
Example

Mass of a steel and a composite car panel

  • A car panel needs 0.0020 m30.0020\,\text{m}^30.0020m3 of material; compare the mass of a steel panel (density 7800 kg/m37800\,\text{kg/m}^37800kg/m3) with a carbon-fibre composite panel (density 1600 kg/m31600\,\text{kg/m}^31600kg/m3).
  • Mass of steel panel =7800×0.0020=15.6 kg= 7800 \times 0.0020 = 15.6\,\text{kg}=7800×0.0020=15.6kg.
  • Mass of composite panel =1600×0.0020=3.2 kg= 1600 \times 0.0020 = 3.2\,\text{kg}=1600×0.0020=3.2kg.
  • Divide the masses: 15.63.2=4.9\dfrac{15.6}{3.2} = 4.93.215.6​=4.9, so the steel panel has about five times the mass of the composite panel.

Choosing a material by matching properties to use

Definition

Brittle

Likely to crack or shatter when hit or bent, rather than changing shape.

  1. List the properties the use needs, such as strength, density, heat resistance or resistance to corrosion.
  2. Then find the material whose values meet every requirement, not the one that is best at only one of them.
  3. Window glass is chosen because it is transparent and hard to scratch, even though it is brittle.
  4. Bricks suit walls because a wall pushes down on them, and clay ceramics are strong when compressed.
  5. Poly(ethene) suits carrier bags and bottles because it has a low density, is flexible and does not react with water.
  6. Steel suits bridges and building frames because it has a high tensile strength, even though it is dense and needs protecting from rust.
Common Mistake

Do not describe a polymer as light, because the property to quote is its low density.

Composites combine materials to offset each other's weaknesses

  1. Reinforced concrete sets steel rods inside concrete, because concrete is strong when compressed and steel is strong when stretched.
  2. Fibreglass sets glass fibres in a polymer resin, giving a strong, low-density material for boat hulls and canoes.
  3. Carbon-fibre composite sets carbon fibres in a polymer resin, giving very high strength with low density for racing bikes and aircraft parts.
  4. Composites are often expensive to make and hard to recycle, because their materials cannot easily be separated.
  5. Wood is a natural composite of cellulose fibres held in a matrix of lignin.
Exam technique

When a question gives a table and asks you to select a material, quote the values that meet each requirement and reject every other material with the value that rules it out.

Self review
  • Roughly how many times denser is steel than poly(ethene)?
  • Why are bricks suitable for walls but not for parts that are stretched?
  • Why are saucepan handles often made of a polymer?
  • Why is reinforced concrete stronger than concrete alone?
  • Why might carbon-fibre composite be chosen instead of steel for a racing bike frame?
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Materials are grouped into ceramics, polymers, composites and metals. In this classification, glass is a type of ceramic. Each class has typical properties, but individual materials within a class can differ widely.

Ceramics, including glass, are usually hard, brittle and resistant to high temperatures. Metals are usually strong, dense and good conductors. Polymers usually have low density and are flexible insulators, while composites combine materials such as fibres in a matrix to produce a useful combination of properties.

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Why is glass suitable for windows despite being brittle?

6.1.7 Comparing and selecting materials Revision Guide

  1. GCSE
  2. /Chemistry
  3. /6.1.7 Comparing and selecting materials

Revision notes for OCR GCSE Chemistry 6.1.7 Comparing and selecting materials: explanations and worked examples.

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