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3.4.1 Using concentrations of solutions in mol/dm3 (chemistry only) (HT only)

3.4.1 Using concentrations of solutions in mol/dm3 (chemistry only) (HT only)

3.4.1 Concentration in mol/dm3

Concentration can be measured in moles per cubic decimetre

Definition

Molar concentration

The concentration of a solution measured in moles of solute per cubic decimetre of solution (mol/dm3\text{mol}/\text{dm}^3mol/dm3).

Definition

Solution

A mixture formed when a solute dissolves in a solvent.

  1. Chemists often give the concentration of a solution in mol/dm3\text{mol}/\text{dm}^3mol/dm3 rather than g/dm3\text{g}/\text{dm}^3g/dm3.
  2. Measuring in moles is useful because reactions happen in whole-number mole ratios, not in equal masses.
Key Idea

A molar concentration tells you how many moles of solute sit in every cubic decimetre of the solution.

Moles, volume and concentration are linked by one formula

Definition

Mole

The amount of a substance, measured in mol, where one mole has a mass in grams numerically equal to its relative formula mass.

  1. The concentration in mol/dm3\text{mol}/\text{dm}^3mol/dm3 is the moles of solute divided by the volume in dm3\text{dm}^3dm3, or c=nVc = \dfrac{n}{V}c=Vn​.
  2. Rearranging gives the moles as n=c×Vn = c \times Vn=c×V and the volume as V=ncV = \dfrac{n}{c}V=cn​.
Example

0.5 mol0.5\ \text{mol}0.5 mol of sodium hydroxide in 250 cm3250\ \text{cm}^3250 cm3 (0.25 dm30.25\ \text{dm}^30.25 dm3) has a concentration of 0.50.25=2 mol/dm3\dfrac{0.5}{0.25} = 2\ \text{mol}/\text{dm}^30.250.5​=2 mol/dm3.

Converting between g/dm3 and mol/dm3

Definition

Solute

The substance dissolved in a solvent to form a solution.

  1. To change g/dm3\text{g}/\text{dm}^3g/dm3 into mol/dm3\text{mol}/\text{dm}^3mol/dm3, divide by the relative formula mass of the solute.
  2. To change mol/dm3\text{mol}/\text{dm}^3mol/dm3 back into g/dm3\text{g}/\text{dm}^3g/dm3, multiply by the relative formula mass.
Exam technique
  • Change the volume to dm3\text{dm}^3dm3 before using c=nVc = \dfrac{n}{V}c=Vn​, as a volume in cm3\text{cm}^3cm3 gives an answer a thousand times too small.
  • Label each concentration with its unit, since mol/dm3\text{mol}/\text{dm}^3mol/dm3 and g/dm3\text{g}/\text{dm}^3g/dm3 are easy to mix up.
Example
  • The sodium hydroxide solution above is 2 mol/dm32\ \text{mol}/\text{dm}^32 mol/dm3.
    1. With Mr=40M_r = 40Mr​=40, this is 2×40=80 g/dm32 \times 40 = 80\ \text{g}/\text{dm}^32×40=80 g/dm3.
    2. Working the other way, 80 g/dm380\ \text{g}/\text{dm}^380 g/dm3 divided by 404040 returns 2 mol/dm32\ \text{mol}/\text{dm}^32 mol/dm3.
Self review
  • What does a concentration in mol/dm3\text{mol}/\text{dm}^3mol/dm3 tell you?
  • Write the formula linking concentration, moles and volume.
  • Find the concentration of 0.2 mol0.2\ \text{mol}0.2 mol of solute in 500 cm3500\ \text{cm}^3500 cm3 of solution.
  • Convert 117 g/dm3117\ \text{g}/\text{dm}^3117 g/dm3 of sodium chloride (Mr=58.5M_r = 58.5Mr​=58.5) into mol/dm3\text{mol}/\text{dm}^3mol/dm3.

Recap questions

1 of 5

A copper sulfate solution has a concentration of 0.40 mol/dm³. How many moles of solute are in 150 cm³ of this solution?

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A solution is a mixture formed when a solute dissolves in a solvent. Molar concentration tells you how many moles of solute are present in every cubic decimetre of solution.

The unit is mol/dm3\text{mol}/\text{dm}^3mol/dm3. Measuring concentration in moles is useful because chemical reactions occur in whole-number mole ratios rather than equal masses.

The key relationship is:

c=nV c = \frac{n}{V} c=Vn​

Here, ccc is concentration in mol/dm3\text{mol}/\text{dm}^3mol/dm3, nnn is amount in mol, and VVV is volume in dm3\text{dm}^3dm3.

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What does a concentration of mol/dm3\text{mol}/\text{dm}^3mol/dm3 tell you?

3.4 Using concentrations of solutions in mol/dm³ (HT only) Revision Guide

  1. GCSE
  2. /Chemistry
  3. /3.4 Using concentrations of solutions in mol/dm³ (HT only)

Revision notes for AQA GCSE Chemistry 3.4 Using concentrations of solutions in mol/dm³ (HT only): explanations and worked examples on 3.4 Using concentrations of solutions in mol/dm³ (HT only).

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