Organic chemistry

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Question 24
Medium

This question is about straight-chain carboxylic acids. Table 1 shows information about some carboxylic acids.

Table 1

Number of carbon atoms in carboxylic acidBoiling point in ∘C^{\circ}\text{C}∘C
1101
2118
3XXX
4164
5186
6205
a.

Predict the boiling point XXX of the carboxylic acid with three carbon atoms.

[1]
b.

A student wants to plot this data on a grid where the vertical scale for boiling point starts at 110 ∘C110\,^{\circ}\text{C}110∘C. Describe why this grid is not suitable to show the boiling point of the carboxylic acid with one carbon atom.

[1]
c.

What is the physical state of the carboxylic acid with one carbon atom at 110 ∘C110\,^{\circ}\text{C}110∘C? Use Table 1.

[1]
d.

The carboxylic acid with six carbon atoms is hexanoic acid. Complete the molecular formula: C6H‾O2\text{C}_6\text{H}_{\underline{\quad}}\text{O}_2C6​H​​O2​

[1]
e.

Hexanoic acid condenses lower down in a fractionating column during fractional distillation than the other carboxylic acids in Table 1. Explain why. You should refer to the temperature gradient in the fractionating column.

[3]

Organic chemistry Questions

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