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Transition elements

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Question 23

A compound of cobalt, K, has the formula NH4[Co(SCN)x(NH3)y]\text{NH}_4[\text{Co}(\text{SCN})_x(\text{NH}_3)_y]NH4​[Co(SCN)x​(NH3​)y​] and contains SCN−\text{SCN}^-SCN− and NH3\text{NH}_3NH3​ ligands.

The percentage by mass of three of the elements in compound K is shown below:

  • Co\text{Co}Co: 17.16%
  • S\text{S}S: 37.35%
  • N\text{N}N: 28.56%

Use the following molar masses: Co=58.9 g mol−1\text{Co} = 58.9\text{ g mol}^{-1}Co=58.9 g mol−1, S=32.1 g mol−1\text{S} = 32.1\text{ g mol}^{-1}S=32.1 g mol−1, and N=14.0 g mol−1\text{N} = 14.0\text{ g mol}^{-1}N=14.0 g mol−1.

a.

Calculate the values of xxx and yyy in the formula of compound K.

[4]
b.

Determine the oxidation number of cobalt in compound K.

[2]

Transition elements Questions

  1. A Level
  2. /Chemistry
  3. /Transition elements