Transition elements

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Question 2
Medium

A coordination compound of iron, Y, has the formula Na2[Fe(CN)x(NH3)y]\text{Na}_2[\text{Fe}(\text{CN})_x(\text{NH}_3)_y]Na2​[Fe(CN)x​(NH3​)y​] and contains CN−\text{CN}^-CN− and NH3\text{NH}_3NH3​ ligands.

The percentage by mass of three of the elements in compound Y is shown below:

  • Fe\text{Fe}Fe: 22.43%
  • C\text{C}C: 24.12%
  • N\text{N}N: 33.76%

Use the following molar masses: Fe=55.8 g mol−1\text{Fe} = 55.8\text{ g mol}^{-1}Fe=55.8 g mol−1, C=12.0 g mol−1\text{C} = 12.0\text{ g mol}^{-1}C=12.0 g mol−1, and N=14.0 g mol−1\text{N} = 14.0\text{ g mol}^{-1}N=14.0 g mol−1.

a.

Calculate the values of xxx and yyy in the formula of compound Y.

[4]
b.

Determine the oxidation number of iron in compound Y.

[3]

Transition elements Questions

  1. A Level
  2. /Chemistry
  3. /Transition elements