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Periodicity

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Question 7

This question is about Group 2 and Group 17.

a.

Barium nitrate can be prepared from barium hydroxide in a neutralisation reaction.

Write the equation for this reaction. State symbols are not required.

[1]
b.

The first ionisation energy of the Group 17 elements F−I\text{F}-\text{I}F−I decreases down the group.

Explain why.

[3]
c.

On heating, the compound KClO3\text{KClO}_3KClO3​ reacts as shown in the equation:

4KClO3(s)→3KClO4(s)+KCl(s) 4\text{KClO}_3(\text{s}) \rightarrow 3\text{KClO}_4(\text{s}) + \text{KCl}(\text{s}) 4KClO3​(s)→3KClO4​(s)+KCl(s)

This reaction is an example of disproportionation.

State what is meant by disproportionation and use oxidation numbers to show that disproportionation has taken place in this reaction.

[3]
d.

What is the systematic name for KClO4\text{KClO}_4KClO4​?

[1]
e.

Two changes are described below.

For each change,

  • write an equation, including state symbols,
  • state and explain how the entropy changes.

The reaction of aqueous barium chloride with aqueous sodium sulfate.

[2]
f.

The change that accompanies the standard enthalpy change of atomisation of iodine.

[2]

Periodicity Questions

  1. A Level
  2. /Chemistry
  3. /Periodicity