An aqueous solution containing [Fe(H2O)6]3+[Fe(H_2O)_6]^{3+}[Fe(H2O)6]3+ ions is mixed with aqueous sodium carbonate, Na2CO3Na_2CO_3Na2CO3. A brown precipitate forms alongside vigorous effervescence.
Which equation and description of the role of [Fe(H2O)6]3+[Fe(H_2O)_6]^{3+}[Fe(H2O)6]3+ correctly represent this reaction?
Equation: 2[Fe(H2O)6]3+(aq)+3CO32−(aq)→2[Fe(H2O)3(OH)3](s)+3CO2(g)+3H2O(l)2[Fe(H_2O)_6]^{3+}(aq) + 3CO_3^{2-}(aq) \rightarrow 2[Fe(H_2O)_3(OH)_3](s) + 3CO_2(g) + 3H_2O(l)2[Fe(H2O)6]3+(aq)+3CO32−(aq)→2[Fe(H2O)3(OH)3](s)+3CO2(g)+3H2O(l)
Role of [Fe(H2O)6]3+[Fe(H_2O)_6]^{3+}[Fe(H2O)6]3+: Brønsted–Lowry acid
Equation: 2[Fe(H2O)6]3+(aq)+3CO32−(aq)→2[Fe(H2O)3(OH)3](s)+3CO2(g)+3H2O(l)2[Fe(H_2O)_6]^{3+}(aq) + 3CO_3^{2-}(aq) \rightarrow 2[Fe(H_2O)_3(OH)_3](s) + 3CO_2(g) + 3H_2O(l)2[Fe(H2O)6]3+(aq)+3CO32−(aq)→2[Fe(H2O)3(OH)3](s)+3CO2(g)+3H2O(l)
Role of [Fe(H2O)6]3+[Fe(H_2O)_6]^{3+}[Fe(H2O)6]3+: Brønsted–Lowry base
Equation: 2[Fe(H2O)6]3+(aq)+3CO32−(aq)→Fe2(CO3)3(s)+12H2O(l)2[Fe(H_2O)_6]^{3+}(aq) + 3CO_3^{2-}(aq) \rightarrow Fe_2(CO_3)_3(s) + 12H_2O(l)2[Fe(H2O)6]3+(aq)+3CO32−(aq)→Fe2(CO3)3(s)+12H2O(l)
Role of [Fe(H2O)6]3+[Fe(H_2O)_6]^{3+}[Fe(H2O)6]3+: Brønsted–Lowry acid
Equation: 2[Fe(H2O)6]3+(aq)+3CO32−(aq)→Fe2(CO3)3(s)+12H2O(l)2[Fe(H_2O)_6]^{3+}(aq) + 3CO_3^{2-}(aq) \rightarrow Fe_2(CO_3)_3(s) + 12H_2O(l)2[Fe(H2O)6]3+(aq)+3CO32−(aq)→Fe2(CO3)3(s)+12H2O(l)
Role of [Fe(H2O)6]3+[Fe(H_2O)_6]^{3+}[Fe(H2O)6]3+: Electron pair donor