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Group 7(17), the halogens

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Question 14
1.

Solid sodium fluoride reacts with concentrated sulfuric acid to produce hydrogen fluoride gas.

  1. Write a balanced chemical equation for this reaction.
  2. State the role of the sulfuric acid in this reaction.
[2]
2.

A gas with a rotten-egg smell and purple fumes are formed when solid sodium iodide reacts with concentrated sulfuric acid.

  1. Write a balanced equation for the reaction of iodide ions with sulfuric acid that produces the rotten-egg smelling gas.
  2. State the role of the sulfuric acid in this reaction.
[2]
3.

Chlorine reacts with hot, concentrated aqueous sodium hydroxide as shown in the equation:

3Cl2+6NaOH→NaClO3+5NaCl+3H2O 3\text{Cl}_2 + 6\text{NaOH} \rightarrow \text{NaClO}_3 + 5\text{NaCl} + 3\text{H}_2\text{O} 3Cl2​+6NaOH→NaClO3​+5NaCl+3H2​O
  1. Determine the oxidation state of chlorine in NaClO3\text{NaClO}_3NaClO3​ and in NaCl\text{NaCl}NaCl.
  2. State, in terms of redox, what happens to chlorine in this reaction.
[2]
4.

Solution Y contains two different negative ions. To a sample of solution Y in a test tube, a student adds:

  • silver nitrate solution
  • then an excess of dilute nitric acid
  • finally an excess of dilute ammonia solution.

The observations after each addition are recorded in the table below:

Reagent added to solution YObservation
silver nitrate solutionWhite precipitate containing compound D and compound E
excess dilute nitric acidWhite precipitate D and bubbles of gas F
excess dilute ammonia solutionColourless solution containing complex ion G
  1. Give the formulas of D, E, and F.
  2. Give an ionic equation to show the formation of E.
  3. Give an equation to show the conversion of D into G.
[5]

Group 7(17), the halogens Questions

  1. A Level
  2. /Chemistry
  3. /Group 7(17), the halogens