Amount of substance

EasyMediumHard
123456789101112131415161718192021222324252627282930313233343536373839404142434445464748495051525354555657
Question 31
Medium

The concentration of a sodium hydroxide solution can be found by titration using a standard solution of ethanedioic acid dihydrate.

1.

Calculate the mass, in g, of solid ethanedioic acid dihydrate (Mr=126.0M_r = 126.0Mr​=126.0) needed to prepare 250 cm3250\text{ cm}^3250 cm3 of 0.0500 mol dm−30.0500\text{ mol dm}^{-3}0.0500 mol dm−3 standard solution.

[2]
2.

The mass of ethanedioic acid dihydrate from Part 1 is dissolved in a beaker containing 80 cm380\text{ cm}^380 cm3 of distilled water. Describe how this solution is used to make 250 cm3250\text{ cm}^3250 cm3 of the 0.0500 mol dm−30.0500\text{ mol dm}^{-3}0.0500 mol dm−3 ethanedioic acid solution.

[4]
3.

Before the first titration, the 25.0 cm325.0\text{ cm}^325.0 cm3 pipette is rinsed with a small volume of the 0.0500 mol dm−30.0500\text{ mol dm}^{-3}0.0500 mol dm−3 ethanedioic acid solution. State why it is good practice to rinse the pipette in this way.

[1]
4.

Sodium hydroxide solution is added to the burette using a funnel. State why it is good practice to remove the funnel from the burette before the titration.

[1]
5.

In a different experiment, 1.42 g1.42\text{ g}1.42 g of solid ethanedioic acid dihydrate is used to make 250 cm3250\text{ cm}^3250 cm3 of standard ethanedioic acid solution. 25.0 cm325.0\text{ cm}^325.0 cm3 of this solution reacts with exactly 23.15 cm323.15\text{ cm}^323.15 cm3 of sodium hydroxide solution. The equation for the reaction is: H2C2O4(aq)+2NaOH(aq)→Na2C2O4(aq)+2H2O(l)\text{H}_2\text{C}_2\text{O}_4(\text{aq}) + 2\text{NaOH}(\text{aq}) \rightarrow \text{Na}_2\text{C}_2\text{O}_4(\text{aq}) + 2\text{H}_2\text{O}(\text{l})H2​C2​O4​(aq)+2NaOH(aq)→Na2​C2​O4​(aq)+2H2​O(l) Calculate the concentration of the sodium hydroxide solution. Give your answer to 3 significant figures.

[4]
6.

The uncertainty in the 25.0 cm325.0\text{ cm}^325.0 cm3 of solution from the pipette is ±0.05 cm3\pm0.05\text{ cm}^3±0.05 cm3. The total uncertainty in the 23.15 cm323.15\text{ cm}^323.15 cm3 of solution from the burette is ±0.10 cm3\pm0.10\text{ cm}^3±0.10 cm3. Calculate the total percentage error in using the pipette and burette. Give your answer to 2 significant figures.

[3]

Amount of substance Questions

  1. A Level
  2. /Chemistry
  3. /Amount of substance